What he studies: High energy chemistry. What it studies: High energy chemistry Journal of high energy chemistry

Scientometric indicators

Usage
  • 6795 Download full texts 2018

    Springer measures the number of full text downloads from the SpringerLink platform according to the COUNTER (Counting Online Usage of NeTworked Electronic Resources) standards.

  • 23 Usage factor 2017/2018

    The utilization factor is a value calculated according to the rules recommended by COUNTER. This is the average (median) number of downloads in 2017/18. for all articles published online in the same journal during the same period. Usage factor calculations are based on data compliant with COUNTER standards on the SpringerLink platform.

Influence
  • 0.634 Impact factor 2018

    Impact factor published by Clarivate Analytics in Journal Citation Reports. Impact factors refer to the previous year.

  • 0.59 Source Normalized Impact per Paper (SNIP) 2018

    Source Normalized Impact per Paper (SNIP) measures the contextual citation impact of a journal by weighting citations within each subject group. The contribution of each individual citation is higher in each specific subject category, the less likely (from considerations of subject content) that such a citation will occur.

  • Q4 Quartile: Physical and Theoretical Chemistry 2018

    A set of journals from the same subject category are ranked according to their SJR and divided into 4 groups called quartiles. Q1 (green) unites journals with the highest scores, Q2 (yellow) - the next ones, Q3 (orange) - the third group by SJR value, Q4 (red) - journals with the lowest scores.

  • 0.27 SCImago Journal Rank (SJR) 2018

    SCImago Journal Rank (SJR) is a measure of a journal's scientific impact that takes into account the number of citations a journal receives and the ranking of citing journals.

  • 19 H-Index 2018

SCOPE

High Energy Chemistry publishes original articles, reviews, and short communications on molecular and supramolecular photochemistry, photobiology, radiation chemistry, plasma chemistry, chemistry of nanosized systems, chemistry of new atoms, processes and materials for optical information systems and other areas of high energy chemistry. It publishes theoretical and experimental studies in all areas of high energy chemistry, such as the interaction of high-energy particles with matter, the nature and reactivity of short-lived species induced by the action of particle and electromagnetic radiation or hot atoms on substances in their gaseous and condensed states, and chemical processes initiated in organic and inorganic systems by high-energy radiation.

Indexing and abstracting

Chemical Abstracts Service (CAS), Chimica, Current Contents/Physical, Chemical and Earth Sciences, EBSCO Academic Search, EBSCO Advanced Placement Source, EBSCO Discovery Service, EBSCO Engineering Source, EBSCO Environment, EBSCO STM Source, Gale, Gale Academic OneFile, Gale InfoTrac, Google Scholar, INIS Atomindex, INSPEC, Institute of Scientific and Technical Information of China, Japanese Science and Technology Agency (JST), Journal Citation Reports/Science Edition, Naver, OCLC WorldCat Discovery Service, ProQuest Central, ProQuest Materials Science and Engineering Database, ProQuest SciTech Premium Collection, ProQuest Technology Collection, ProQuest-ExLibris Primo, ProQuest-ExLibris Summon, Reaction Citation Index, Reaxys, SCImago, SCOPUS, Science Citation Index, Science Citation Index Expanded (SciSearch), Semantic Scholar.

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AGREEMENT - PUBLIC OFFER

Federal State Unitary Enterprise "Publishing House "Nauka" represented by Acting Director Dmitry Pavlovich Korotkov, acting on the basis of the Charter, hereinafter referred to as "Publishing house", on the one hand, and the Internet user, hereinafter referred to as "User", on the other hand, collectively referred to as the “Parties”, have entered into this agreement (hereinafter referred to as the “Agreement”)

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2. Terms used in the Agreement

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2.2. Works (Content) – electronic versions of scientific publications, including periodicals, as well as non-periodical publications, presented electronically on the Internet in various formats, posted on the Website of the Electronic Library System, accessible to Users through the Website of the Electronic Library System.

2.3. Catalog – a collection of Works.

2.4. Login and Password are two unique sets of characters that identify the User.

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2.7. Downloading – recording by the User of Works into the computer memory.

2.8. Billing is a payment accounting system.

2.9. User Account – Authentication and personal data of the User stored on the servers of the Electronic Library System Site. An account is created as a result of the User's registration procedure and may be required in order to take advantage of certain features or certain functions of the Site.

3. Subject of the Agreement

3.1. The “Electronic Library System” provides the User with the opportunity to view, read and download Works presented in the Catalog on a paid basis.

3.2. The user can register and pay for a preliminary annual (partial annual) subscription for the ability to view, read and download electronic versions of Works, as well as a preliminary subscription for the opportunity to receive a collection of Works that are not posted in the Catalog at the time of registration and payment.

4. Responsibilities of the parties

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4.1.1. Provide the User with the opportunity to view, read and download the Work on the Site no later than 24 hours from the moment Billing confirms the payment made and identifies the User as the payer of the payment made. If the User registers and pays for a preliminary subscription in accordance with clause 3.2. Agreement, to provide the User with the opportunity to view, read and download the Work no later than 24 hours from the moment of their placement in the Catalog, subject to confirmation by Billing of the previously made payment and identification of the User as the payer of the payment made.

4.1.2. Do not disclose to third parties the Login and Password, the User’s email address, as well as other information received from the User during registration.

4.1.3. Notify the User of changes to the terms of the Agreement and its Appendices by posting relevant information on the Electronic Library System Website at least 30 (thirty) calendar days before the changes come into force.

4.2. User Responsibilities:

4.2.1. Register on the “Electronic Library System” website. Set a Login and Password, the uniqueness of which is confirmed by the “Site Administration”. At the same time, strictly and strictly follow the instructions of the Site Administration on the registration procedure posted on the “Electronic Library System” Site.

4.2.2. Pay for the opportunity to view, read and download Works in accordance with clause 4 of the Agreement.

4.2.3. Ensure the confidentiality of the Login and Password provided during registration.

4.2.4. Use the downloaded Works exclusively for personal purposes. In this case, the User is granted the following rights to use the Works:

  • provide remote access on the Internet through the Website of the Electronic Library System to Works, which means the ability to search, view, download and read Works.
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  • Failure by the User to comply with the requirements of clause 4.2.5. The Agreement is a violation of copyright law and entails the consequences specified in clause 10.1 and clause 10.2 of the Agreement.

4.2.6. All information posted on the Electronic Library System Website about the procedure for using the Catalog, the payment procedure and other features of the execution of the Agreement is an integral part of the Agreement and is binding on the User.

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5.4. The price for providing the User - an individual with the opportunity to view, read and download Works is indicated on the Website of the Electronic Library System in the relevant sections. For users who are legal entities, prices are sent by the “Site Administration” upon request through agreed communication channels. The “Site Administration” has the right to unilaterally change current prices by posting relevant information on the Website of the “Electronic Library System” or informing Users in any other accessible way. Any price change does not affect already paid access.

6. Responsibility of the parties. Limitation of liability of the Electronic Library System.

6.1. The User assumes full responsibility and risks associated with the use of the Catalog.

6.2. The User is fully responsible for the use of the Login and Password by third parties.

6.3. The User is fully responsible for the use by third parties of information transmitted by the “Site Administration” to the email address specified by the User during registration.

6.4. The “Site Administration” is not responsible for any expenses of the User or direct or indirect damage that may be caused to the User as a result of using the Catalog.

6.5. The “site administration” is not responsible for the quality of access to the Catalog via the Internet.

6.6. Under no circumstances is the “Site Administration” liable for the use of the Login and Password by third parties.

6.7. The “site administration” is not responsible for direct or indirect damage incurred by the User as a result of data transmission errors, failures/defects in the operation of software and/or equipment, data loss and damage, errors in processing or displaying data, delays in data transmission and others failures that occurred through no fault of the Site Administration.

6.8. The Electronic Library System website and all related services are provided on an “as is” basis, without any express or implied warranties that the said Website and/or services may or may not be suitable for a particular purpose of use.

6.9. The “Site Administration” is not responsible for the inability to use the Site and (or) related services by the User for any reason, including, but not limited to: errors, omissions, interruptions, deletion, defects, delay in processing or transmission of data, disruption of work communication lines, equipment malfunction, any technical failures or other problems of any telephone networks or services, computer systems, servers or providers, computer or telephone equipment, software, failure of providers of certain services, theft, destruction or unauthorized access to User materials , posted on the Site or in any other place, etc.

6.10. Under no circumstances is the “Site Administration” liable for any expenses of the User or direct or indirect damage, including lost profits or lost data, damage to honor, dignity or business reputation that may be caused to the User as a result of using the Site and (or) related services .

6.11. If it is impossible for the “Electronic Library System” to provide the User with the opportunity to view, read and download the Work for reasons beyond the control of the “Site Administration”, the “Site Administration”, at the request of the User, returns the received advance payment. In this case, the amount of responsibility of the “Site Administration” is limited to the amount of the advance payment received from the User for the opportunity to view, read and download the Work, which was not provided.

7. Duration of the Agreement

7.1. The Agreement comes into force from the moment the User accepts the terms of the Agreement (each Appendix to the Agreement comes into force from the moment the User accepts the terms of this Appendix) and is valid until the Parties fully fulfill their obligations.

8. Force majeure circumstances

8.1. The parties are released from liability for partial or complete failure to fulfill obligations under this Agreement if such failure was a direct consequence of force majeure circumstances (force majeure circumstances) that arose after the conclusion of the Agreement, as a result of extraordinary events, namely: fire, flood, hurricane and earthquake or restrictions imposed by government authorities on the activities of any of the Parties, and if these circumstances could not be foreseen or prevented by the Parties by reasonable measures.

9. Other conditions

9.1. In the event that any provision or any part of the Agreement is held to be invalid or unenforceable, the remaining provisions and portions of the Agreement will remain in full force and effect.

9.2. In all other respects, the Parties to the Agreement agreed to be guided by the current legislation of the Russian Federation.

9.3. The “Site Administration” has the right to make changes to the Agreement with the obligatory posting of the relevant information on the Website of the “Electronic Library System” no later than 30 (thirty) calendar days before the relevant changes come into force.

9.4. Relations between the “Site Administration” and the User, who are legal entities, are regulated on the basis of separately concluded Agreements, which specify the specific terms of the relationship between the Parties.

9.5. For any questions that arise, the User has the right to contact the Site Support Service at the following email address:

10. Dispute resolution

10.1. Disputes and disagreements that may arise under this Agreement are resolved by following the pre-trial (claim) procedure. The period for consideration by the Site Administration of a claim is 10 (Ten) calendar days from the date of its receipt from the User.

10.2. If the Parties do not come to an agreement, these disputes and disagreements are resolved in court in accordance with the current legislation of the Russian Federation in the court at the location of the Federal State Unitary Enterprise “Publishing House “Nauka”” in accordance with the rules of jurisdiction and jurisdiction.

11. Privacy Notice

11.1. The User's consent to provide personal information is determined by agreement with this public offer, which occurs automatically when the User goes through the registration procedure on the Site.

11.2. In accordance with Federal Law“On Personal Data” No. 152-FZ of July 27, 2006 and this privacy policy, the Site Administration does not use, process or store the User’s personal data.

11.3. The “Site Administration” collects and stores only the User data necessary for the operation of the Site. The “site administration” can use the User’s data to identify him, clarify payment data, provide personalized services, provide feedback to the User, process applications and requests, perform impersonal statistical calculations and improve the quality of services provided to the User.

The journal publishes original and review articles, short communications, letters to the editor on molecular and supramolecular photochemistry, radiation chemistry, plasma chemistry, chemistry of new atoms, processes and materials for optical information systems, on the scientific basis of relevant technologies, as well as chronicles and reviews of books in the field of high energy chemistry.

From the second half of 2007, the magazine will publish materials on topics of scientific and applied photography. Previously (until 2003), the Journal of Scientific and Applied Photography was published as an independent publication.

Archive of scientific articles from the journal “High Energy Chemistry”

  • J-aggregation of thiacarbocyanine dye in inverse microemulsions

    BRICHKIN S.B., IVANCHIKHINA A.V., NEVIDIMOV A.V., NIKOLENKO L.M., RAZUMOV V.F., TOVSTUN S.A. - 2015

    J-aggregation of the thiacarbocyanine dye pyridinium salt 3,3-di-(-sulfopropyl)-4,5,4,5-dibenzo-9-ethylthiacarbocyanine betaine (DEC) in reverse microemulsions of sodium bis-(2-ethylhexyl) sulfosuccinate (AOT) was studied )/n-hexane/water and polyoxyethylene (5) nonylphenyl ether (NP5)/cyclohexane/water. In such systems, the dye is present mainly in the form of a trans-monomer and a J-aggregate. It has been shown that the equilibrium between these forms is determined by the solubility of the trans-monomer in monolayers of surfactant molecules covering microemulsion droplets. When the total concentration of the dye in the microemulsion is less than the solubility, the equilibrium state corresponds to the presence of the dye only in the form of a trans-monomer. When the concentration exceeds the solubility, the excess dye forms J-aggregates, which gradually become larger and precipitate. For reverse AOT/n-hexane/water microemulsions, the solubility found was / = (1.45 ± 0.34) ? 10-5.

  • LASER PLASMA INTERACTION DURING VISIBLE AND IR LASER ABLATION OF CHROMITE MINERAL TARGET

    HANIF M., SALIK M., WANG J., ZHANG X.Q. - 2015

    In this work, we present optical emission studies of the laser induced Chromite mineral plasma produced by the fundamental (1064 nm) and second (532 nm) harmonics of a Q-switched pulsed Nd: YAG laser. The spectra predominantly reveal the spectral lines of neutral Cr as well as dominant spectral lines of constituent elements. The experimentally observed line profiles of neutral chromium have been used to extract the electron temperature (Te) using Boltzmann plot method. Whereas, the electron number density (Ne) has been determined from the Stark broadened line profiles. We have also studied the variation of electron temperature and electron number density as a function of laser irradiance at atmospheric pressure. We have also studied the variation of these plasma parameters (Te and Ne) as a function of the laser irradiance as well as distance along the direction of plasma plume. The validity of the assumption of local thermodynamic equilibrium (LTE) is also discussed in the light of the experimental data and analysis.

  • PREPARATION OF COLLOIDAL LEAD SULFIDE NANOPARTICLES BY LASER ABLATION IN WATER FOR OPTOELECTRONIC DEVICES APPLICATIONS

    ISMAIL RAID A. - 2015

    In present work, lead sulfide PbS nanoparticles NPs are synthesized by laser ablation of lead sulfide target in double distilled water using 0.532 and 1.064 wavelengths. The transmission electron microscopy TEM, atomic force microscopy AFM and X-ray diffraction XRD were used so as to determine the shape, size, distribution, and structure of the nanoparticles prepared with different laser wavelengths. X-ray diffraction results confirmed that the lead sulfide nanoparticles crystallized in the cubic phase and presents a preferential orientation along (200) plane and with no observation of any incomplete phases. Optical band gap values ​​of 1.9 and 2eV for the lead sulfide nanoparticles were determined by UV-Vis absorption measurements. It was found that the morphology and size of PbS NPs depend on laser wavelength. To check the possibility of synthesised nanoparticles for optoelectronic devices, a novel type of solution-processed heterojunction photodetector, prepared by drop cast film of colloidal lead sulfide nanoparticles NPs onto n-type single crystal silicon wafer was demonstrated. The effect of laser wavelength on the electrical characteristics and photosensitivity of p-PbS/n-Si heterojunction has been investigated.

  • THERMOLUMINESCENCE RESPONSE OF MULTIMODE FLUORINE-DOPED SIO2 OPTICAL FIBERS AND TLD 100 WITH 6 MEGA VOLT PHOTON IRRADIATION

    HOSSAIN I., MUBARAK A.A., NURSYAZWANIE R., SAEED M.A., WAGIRAN H. - 2015

    This study investigates and compares the results of thermoluminescence responses, its linearity, sensitivity with various dose ranges and TL glow curve of Fluorine-doped silica fiber and TLD-100 materials. The TL responses of the Fl-doped silica fibers and TLD 100 were kept in gelatin capsule and irradiated with 6-MV photon at the dose range from 0.5 Gy to 4.0 Gy. Siemens model Primus 3368 linear accelerator located at Hospital Sultan Ismail; Johor Bahru has been used to deliver the photon beam to the samples. The TL-signal of TLD 100 media exhibits a significant linear dose to signal relationship with an increase in doses. The sensitivity of Fl-doped optical fiber is negligible to TLD 100 media.

  • THERMOLUMINESCENCE RESPONSE OF YTTERBIUM-DOPED SILICON DIOXIDE FIBER

    ABDUL PATTAH N.F., HOSSAIN I., SAEED M.A., WAGIRAN H. - 2015

    In this study, thermoluminescence properties of Yb-doped of SiO2 optical fiber such as linearity, sensitivity and dose response have been studied. Samples were placed in the gelatin capsules to irradiate with photons from Cobalt-60 of the dose range between 10100 Gy. The beams were provided by Gammacell 220, available at Universiti Kebangsaan Malaysia, Bangi, Malaysia. The glow curves were analyzed to determine various characteristics of the thermoluminescence. The TL response as a function of dose is linear up to 40 Gy. The sensitivity of Yb-doped optical fiber is 0.136 nC mg-1 Gy-1.

  • TIME FUNCTION TRIPLE LANGMUIR PROBE MEASUREMENTS IN LOW FREQUENCY PULSED DC DISCHARGE PLASMA

    ALI A., FAROOQ M.U., GHAFFAR CH. A., KHAN Y., NAZ M.Y., QAYYUM A., SHUKRULLAH S. - 2015

    This study investigated the temporal profiles of electron temperature and number density in rectified DC air discharge generated with a 50 Hz step-up transformer. An in-house built triple Langmuir probe and circuitry were used to diagnose the plasma parameters as a function of input voltage and filling gas pressure. A tungsten metal wire capable of withstanding the high temperatures was used as probe tip material. The temporal profiles revealed an increase in electron temperature with input voltage in the range of 380 to 450 V, whereas, an inverse relation between number density and input voltage was evident in the given work. The observed trend in the plasma parameters was absolutely reversed in case of the filling gas pressure. The electron temperature linearly decreased with an increase in pressure from 1 to 4 mbar, whereas a linear increase in number density with pressure was seen in the temporal profiles. Finally, it was concluded that the results for the tested plasma parameters were consistent and the in-house built probe functioned well in DC discharge for the used range of voltage and filling pressure.

  • INTERACTION OF TRYPTOPHAN AND ITS DERIVATIVES WITH OXYGEN AND NITROGEN CENTERED RADICALS

    BRINKEVICH S.D., SVERDLOV R.L., KHRISTHANOVICH A.V., SHADYRO O.I. - 2015

    The interaction of tryptophan and its derivatives with nitrogen-centered 2,2-diphenyl-1-picrylhydrazyl radicals and oxygen-centered radicals formed during the radiolysis of oxygen-saturated ethanol and its aqueous solutions was studied. It has been established that tryptophan, 5-hydroxytryptophan, serotonin, harmane, harmine and harmaline, in contrast to pyrrole, indole and melatonin, are capable of reducing oxygen-centered radicals due to the reaction of electron transfer from a lone pair of nitrogen atoms. It has been shown that serotonin and 5-hydroxytryptophan reduce 2,2-diphenyl-1-picrylhydrazyl radicals due to the reaction of hydrogen atom transfer from the hydroxyl groups of molecules. In this case, pyrrole, indole, tryptophan, melatonin, harmane, harmine and harmaline, which do not contain a phenolic-type hydroxyl group in their structure, do not interact with 2,2-diphenyl-1-picrylhydrazyl radicals. Using chromatography-mass spectrometry, the final molecular products of the interaction of serotonin and 5-hydroxytryptophan with 2,2-diphenyl-1-picrylhydrazyl radicals were identified.

  • RELATIONSHIP OF ADHESIVE, CONTACT AND ELECTRET PROPERTIES OF POLYTETRAFLOOROETHYLENE FILMS MODIFIED IN DC DISCHARGE

    GILMAN A.B., KECHEKYAN A.S., KUZNETSOV A.A., PISKAREV M.S., YABLOKOV M.YU. - 2015

    The relationship between the values ​​of the contact angle, peel resistance, and effective surface charge density of polytetrafluoroethylene films modified in a direct current discharge at the anode and cathode has been studied. It has been shown that there is a correlation between the adhesion characteristics of the film treated in a direct current discharge, the change in the contact angle and the value of the effective surface charge.

  • VIBRONIC STRUCTURE OF ELECTRON ABSORPTION AND FLUORESCENCE SPECTRA OF PYRENE IN COMPLEX WITH BETA-CYCLODEXTRIN IN THE PRESENCE OF NON-POLAR AND POLAR SOLVENTS

    VAKYAN V.G., ALFIMOV M.V., KOSHKIN A.V., NAZAROV V.B. - 2015

    The possibility of using pyrene (Py) as a fluorescent probe (FP) in cyclodextrin-pyrene-analyte complexes for analytes (A) of various polarities in aqueous solutions was investigated. In the UV-VIS spectrum of an aqueous solution of Py in the presence of CD, bands were found for the first time indicating the formation of the Py@2 CD complex. A characteristic of the FC is the ratio I3/I1 in the fluorescence spectrum, where I3 is the intensity of the third vibronic line 800 cm-1, I1 is the intensity of the 0-0 transition. The I3/I1 value for Py@2 CD exhibits high sensitivity to the addition of A at a concentration of several M/L to an aqueous solution. The dependences (I3/I1)/C on the dielectric constant function A f = ( 1)/2 + 1) are divided into two straight lines with different slopes for non-polar and polar A. The insertion energies of A in Py@2 CD are calculated by quantum chemical PM3 method. The increase in (I3/I1)/C corresponds to the thermodynamically more stable complex 2A · Py@2 CD.

  • INFLUENCE OF ALBUMIN AND WATER-SOLUBLE ANALOGUES OF VITAMINS E, Q, K ON FREE RADICAL FRAGMENTATION OF PHOSPHOLIPIDS

    MELSITOVA I.V., YURKOVA I.L. - 2015

    The influence of Trolox C, ubiquinone Q0, Phticol and bovine serum albumin (BSA) on the free radical fragmentation of dimyristoylphosphatidylglycerol (DMPG) in model membranes exposed to -radiation was studied. It has been established that ubiquinone Q0 and phthikol are more effective (1.8 1.9 times) in comparison with Trolox C (1.5 times) in reducing the radiation-chemical yield of dimyristoylphosphatidic acid (DMPA), a molecular product of DMPG fragmentation. BSA has a protective effect on DMPH fragmentation in a dose-dependent manner; at a lipid:protein ratio (30:1), the yield of DMPH is reduced by 2 times.

  • INFLUENCE OF ASCORBIC ACID AND ITS DERIVATIVES ON RADIATION-INDUCED TRANSFORMATIONS OF OXYGENATED ETHANOL AND ITS AQUEOUS SOLUTIONS

    BRINKEVICH S.D. - 2015

    When -irradiation of ethanol and its aqueous solutions at pH 7, saturated with oxygen, ascorbic acid is capable of reducing the yields due to the reduction of peroxyl radicals, and 5,6-O-isopropylidel-2,3-O-dimethylascorbic acid due to the oxidation of -hydroxyethyl radicals main products of radiolysis. In addition to the ability to inhibit radiation-induced transformations of oxygenated ethanol and its aqueous solutions at pH 7, ascorbic acid can enter into reactions leading to the formation of additional amounts of reactive oxygen species, which must be taken into account when considering its role in free radical processes in biosystems.

  • INFLUENCE OF HYPOCHLORITE ON RADIOLYSIS OF AQUEOUS PROPANOL-2

    KOSOBUTSKY V.S. - 2015

    DOI: 10.7868/S0023119315040105 References

  • INFLUENCE OF LIGHTING INTENSITY ON THE RATE AND SELECTIVITY OF PHOTOSENSITIZED OXIDATION OF DIBUTYL SULPHIDE ON C70 FULLERENE

    Arsentiev A.V., Vorontsov A.V., PARMON V.N. - 2015

    Photoinitiated oxidation of dibutyl sulfide (DBS) with atmospheric oxygen in a toluene solution of C70 fullerene under illumination with visible light with a wavelength of 500 x 700 nm leads to the formation of dibutyl sulfone as the main detected product, as well as dibutyl sulfoxide, dibutyl disulfide and butanal. A change in the irradiation of the reaction mixture from 2.2 to 44 mW/cm2 slightly increases the quantum efficiency of DBS consumption from 4.5 to 5.9%. In this case, the selectivity of sulfoxide formation increases and the selectivity of sulfone formation decreases.

  • INFLUENCE OF PARAMETERS OF DIELECTRIC BARRIER DISCHARGE OF ATMOSPHERIC PRESSURE IN OXYGEN ON THE KINETICS OF SULPHONOL DECOMPOSITION IN WATER

    BOBKOVA E.S., BORZOVA A.A., RYBKIN V.V., SHISHKINA A.I. - 2015

    The kinetics of the decomposition of sulfonol and the formation of its destruction products when an aqueous solution is exposed to a dielectric barrier discharge of atmospheric pressure in oxygen in the power range of 0.44 W was measured. It has been shown that the decomposition products in the liquid phase are carboxylic acids, aldehydes and carbon dioxide in the gas phase. The energy efficiency of decomposition was determined, which was (4.412.7) ? 10-3 molecules per 100 eV of energy input. Assumptions have been made about the mechanisms of the ongoing processes.

  • INFLUENCE OF THE NATURE OF ANION OF CATIONIC POLYMETHINE DYES ON PHOTOVOLTAIC PROPERTIES OF POLYMER PHOTOSEMICONDUCTOR COMPOSITES

    BULAVKO G.V., DAVIDENKO N.A., DEREVYANKO N.A., ISCHENKO A.A. - 2015

    It was found that the nature of the anion of cationic polymethine dyes in polymer solar cells affects the photovoltage. Based on a study of spectral and luminescent properties, it was established that polymethines in them form contact ion pairs. It is shown that the difference in the behavior of anions is determined by their ability to photoinduced electron transfer in these pairs.

  • INFLUENCE OF A HEAVY CENTRAL ATOM ON THE PHOTOELECTRICAL, NON-LINEAR OPTICAL AND PHOTOREFRACTIVE PROPERTIES OF METAL PHTHALOCYANINES

    VANNIKOV A.V., GORBUNOVA Y.G., GRISHINA A.D., ZOLOTAREVSKY V.I., KRIVENKO T.V., LAPKINA L.A., LARUSHKIN A.S., SAVELIEV V.V., TSIVADZE A .YU. - 2015

    Measurements of the photoelectric and photorefractive characteristics of yttrium(III) 2,3,9,10,16,17,23,24-tetra(15-crown-5)phthalocyaninato-acetate [(15C5)4Pc]Y(OAc) made it possible to reliably establish the course a decrease in the quantum yield of formation of charge carriers 0 and the coefficient of photorefractive two-beam enhancement as the atomic weight of the central metal increases in the series of related gallium(III), yttrium(III), ruthenium(II) and indium(III) phthalocyaninates. The revealed patterns may be due to an increase in the spin-orbit interaction constant as the atomic weight of the central metal increases, which leads to an increase in both the contribution of triplet-excited associates to the formation of mobile charge carriers and the rate of the reverse reaction T1 S0, which effectively suppresses the formation of charge carriers through triplet excited state. Measurements of photoelectric and photorefractive characteristics at 1064 nm showed that in the polyvinylcarbazole/supramolecular ensembles of the yttrium complex the quantum yield of electron-hole pairs is 0 = 0.6 and the double-beam gain of the laser beam is about = 35 cm-1 at E0 = 120 V/μm. The dielectric susceptibility measured by z-scanning of a solution of the yttrium complex in tetrachloroethane (1 mg in 1 ml) is (3) = 4.2? 10-10 esu.

  • GAMMA RADIOLYSIS OF THE BINARY SYSTEM “ETHANOL–WATER” IN THE PRESENCE OF OXYGEN

    MARCHENKO N.V., NIKITIN A.V., SAZONOV A.B. - 2015

    Studies of gamma radiolysis of an aerated “ethanol-water” system in a wide range of component concentrations show that the main process occurring in such a system is the selective radiation oxidation of ethanol to acetaldehyde. By-products that accumulate in the liquid phase are 2,3-butanediol and formaldehyde. The selectivity of the process increases with increasing alcohol content and decreases with increasing radiation dose. The theoretical model of radiolysis created within the framework of the work gives good quantitative agreement with experimental data. The calculated product accumulation curves have turning points, characterized by a sharp change in the radiation-chemical yield. Their occurrence is associated with the complete burnout of oxygen in a closed system or with its insufficiently rapid entry into the liquid in a two-phase “liquid-gas” system.

  • HOLOGRAPHIC MEDIUM BASED ON HALOGEN-CONTAINING CO-OLIGOMER

    GETMANCHUK Y.P., DAVIDENKO I.I., DAVIDENKO N.A., MOKRINSKAYA E.V., PAVLOV V.A., CHUPRINA N.G. - 2015

    The information properties of recording media for the photothermoplastic method of recording holograms with films of oligomeric composites based on carbazolyl-containing co-oligomers, one of which contains Br atoms, have been studied. A medium based on a Br-containing co-oligomer has greater holographic sensitivity due to a higher discharge rate of the film surface during exposure and the formation of a latent electrostatic image.

  • STUDYING THE INFLUENCE OF CHARGE ACCEPTORS ON THE PROCESS OF RADIATION-CHEMICAL CARBOXYLATION OF THE INDOLE–SERINE SYSTEM

    ZHIGUNOVA L.N., NICHIPOR G.V., SHEVTSOVA O.V. - 2015

    Considerable interest in the radiation-chemical carboxylation of the indole-serine system is due to the prospect of its use to obtain the essential amino acid tryptophan. In this work, we study the influence of charge acceptors biphenyl and hydrogen peroxide on the kinetics of radiolysis of the system. It has been established that the solvated electron plays a decisive role in the mechanism of tryptophan formation.

  • PULSE HEATING OF WATER NEAR THE SURFACE OF GOLD NANOPARTICLES: FEMTOSECOND LASER SPECTROSCOPY OF ENERGY RELAXATION OF AN AQUEOUS COLLOID OF PLASMON NANOPARTICLES UNDER CONDITIONS OF STRONG EXCITATION

    AIBUSH A.V., ASTAFIEV A.A., GOSTEV F.E., DENISOV N.N., NADTOCHENKO V.A., TITOV A.A., SHAHOV A.M., SHELAYEV I.V. - 2015

    The dynamics of differential absorption spectra of gold nanoparticles in a wide range of excitation energy densities was studied using femtosecond laser spectroscopy. The position of the plasmon resonance peak depends significantly on the dielectric properties environment, which allows the use of plasmonic nanoparticles as an optical probe. This work demonstrates the possibility of using femtosecond laser spectroscopy, based on the analysis of differential absorption spectra of gold nanoparticles in an aqueous colloid, to characterize the state of the water nanolayer surrounding the nanoparticle. In particular, at high excitation energy densities, spectral and kinetic features are revealed in the plasmon resonance absorption band, which indicate vapor formation in the nanolayer around the gold particle.

High Energy Chemistry [ Electronic resource] .- 2017 .- No. 2 .- 84 p. - Access mode: https://site/efd/556147

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FEATURES OF THE MOLECULAR-TOPOLOGICAL STRUCTURE OF GAMMA-IRRADIATED POWDER COPOLYMER OF TETRAFLUOROETHYLENE WITH PERFLUOROVINYLPROPYL ETHER / Allayarov (200.00 rub.)
RADIATION POLYMERIZATION OF METHACRYLATES CONTROLLED BY A CHAIN ​​TRANSFER CATALYST / Roshchupkin (RUB 200.00)
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INFLUENCE OF GAMMA RADIATION AND THERMAL ANNEALING ON THE MOLECULAR-TOPOLOGICAL STRUCTURE OF THE COPOLYMER OF TETRAFLUOROETHYLENE AND PERFLUOROPROPYL VINYL ETHER / Olkhov (RUB 200.00)
SPECTRAL-LUMINESCENCE AND QUANTUM-CHEMICAL STUDY OF ANIONIC FORMS OF 5-FLUOROURATIL / Ostakhov (200.00 rub.)
INFLUENCE OF SUBSTITUTES ON SPECTRAL, LUMINESCENCE AND SPECTRAL-KINETIC PROPERTIES OF 2,5-DIARYLIDENE DERIVATIVES OF CYCLOPENTANONE / Zakharova (200.00 rub.)
INFLUENCE OF ALKANTHIOLS ON THE FLINKERING OF FLUORESCENCE OF COLLOIDAL QUANTUM DOTS INP@ZNS / Gak (200.00 rub.)
OPTIMIZATION OF THE PROCESS OF PLASMA PROCESSING OF AQUEOUS SOLUTIONS OF SODIUM CHLORIDE / Nikolenko (RUB 200.00)
CONVERSION OF HYDROCARBON GASES IN A BARRIER DISCHARGE IN THE PRESENCE OF WATER / Kudryashov (RUB 200.00)
EXPERIMENTAL STUDY OF VAR GASIFICATION IN A molten METAL DURING CYCLIC FEEDING OF CARBON-CONTAINING RAW MATERIALS AND OXIDIZER INTO THE REACTOR / Babaritsky (200.00 rub.)
MODIFICATION OF ULTRA-HIGH MOLECULAR POLYETHYLENE IN LOW-TEMPERATURE PLASMA (REVIEW) / Gilman (RUB 200.00)
NEW DATA ABOUT THE COMPOSITION OF PRODUCTS OF ULTRASONIC IRRADIATION OF GRAPHITE IN N-METHYL PYRROLIDONE / Shulga (200.00 rub.)
TRIPLETED STATES OF BIS-CARBOCYANINE DYE AND ALBUMIN COMPLEXES / Kostyukov (RUB 200.00)

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Chemistry_of_high_energies_No. 2_2017.pdf

CONTENTS Volume 51, number 2, 2017 RADIATION CHEMISTRY Features of the molecular topological structure of gamma-irradiated powder copolymer of tetrafluoroethylene with perfluorovinylpropyl ether S. R. Allayarov, Yu. A. Olkhov, N. N. Loginova, I. I. Sadikov, M. Yu. Tashmetov Radiation polymerization of methacrylates controlled by a chain transfer catalyst V. P. Roshchupkin, M. P. Berezin, D. P. Kiryukhin Generation of hydrogen by hydroreactive compositions with γ-irradiated aluminum V. K. Milinchuk, E. R. Klinshpont , V. I. Belozerov Radiation synthesis of tetrafluoroethylene telomers in chlorosilanes and their use for modifying aluminoborosilicate glass fabric G. A. Kichigina, P. P. Kushch, D. P. Kiryukhin The influence of gamma irradiation and thermal annealing on the molecular topological structure of tetrafluoroethylene copolymer and perfluoropropyl vinyl ether Yu. A. Olkhov, S. R. Allayarov, R. S. Allayarov, D. A. Dixon PHOTONICS Spectral-luminescent and quantum chemical study of anionic forms of 5-fluorouracil S. S. Ostakhov, M. V. Sultanbaev, M. Yu. Ovchinnikov, R. R. Kayumova, S. L. Khursan Effect of substituents on the spectral, luminescent and spectral-kinetic properties of 2,5-diarylidene derivatives of cyclopentanone G. V. Zakharova, F. S. Zyuzkevich, V N. Gutrov, G. V. Gavrilova, V. N. Nuriev, S. Z. Vatsadze, V. G. Plotnikov, S. P. Gromov, A. K. Chibisov Effect of alkanethiols on the fluorescence flicker of colloidal quantum dots InP@ ZnS V. Yu. Gak, S. A. Tovstun, M. G. Spirin, S. B. Brichkin, V. F. Razumov PLASMOCHEMISTRY Optimization of the process of plasma treatment of aqueous solutions of sodium chloride N. V. Nikolenko, R. I. Zakharov , A. V. Dubenko, G. V. Moleva, T. N. Avdienko Conversion of hydrocarbon gases in a barrier discharge in the presence of water S. V. Kudryashov, A. Yu. Ryabov, A. N. Ocheredko Experimental study of gasification of tar in the melt metal during cyclic feeding of carbon-containing raw materials and oxidizer into the reactor A. I. Babaritsky, M. B. Bibikov, M. A. Deminsky, S. A. Demkin, S. V. Korobtsev, M. F. Krotov, B. V. Potapkin, R.V. Smirnov, F.N. Chebankov Modification of ultra-high molecular weight polyethylene in low-temperature plasma (Review) A.B. Gilman, M.S. Piskarev, A.A. Kuznetsov, A.N. Ozerin 147 142 131 137 121 126 116 109 103 99 94 85

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SONOCHEMISTRY New data on the composition of products of ultrasonic irradiation of graphite in N-methylpyrrolidone Yu. M. Shulga, A. S. Lobach, F. O. Milovich, N. Yu. Shulga, D. A. Kiselev, S. A. Baskakov BRIEF COMMUNICATIONS PHOTOCHEMISTRY Triplet states of complexes of bis-carbocyanine dye and albumin A. A. Kostyukov, T. D. Nekipelova, A. Sh. Radchenko, G. V. Golovina, O. N. Klimovich, A. A. Shtil, Debora C. K. Codognato, Pablo J. Gonçalves, André L. S. Pavanelli, Lucimara P. Ferreira, Andre M. Amado, Yu. E. Borisevich, V. A. Kuzmin 161 157 Submitted for typesetting 11/7/2016 Signed for printing 01/16/2017 Digital printing Conditional oven l. 10.25 Cond. cr.-ott. 0.6 thousand. Circulation 52 copies. Zak.84 Date of publication 03.23.2017 Format 60 Ch 881/8 Academic ed. l. 10.25 Boom. l. 5.1 Free price Founders: Russian Academy Sciences, Center for Photochemistry of the Russian Academy of Sciences Publisher: Russian Academy of Sciences. Publishing house “Nauka”, 117997, Moscow, Profsoyuznaya st., 90 Original layout prepared by MAIK “Nauka/Interperiodika” Printed in the printing house “Nauka”, 121099, Moscow, Shubinsky per., 6